Your search found 5 records
1 Cofie, Olufunke; Pleysier, J. 2004. Ion exchange involving calcium-potasium (Ca-K) and calcium-magnesium (Ca-Mg) in soil and organic matter fractions. Communications in Soil Science and Plant Analysis, 35(17-18):2417-2431.
Ion exchange ; Soil properties ; Soil organic matter ; Clay ; Fractionation ; Calcium ; Magnesium ; Potassium / Nigeria
(Location: IWMI-HQ Call no: IWMI 631.4 G000 COF Record No: H035917)
The chemical characteristics of two soil types, an Alfisol and an Ultisol, were studied in the humid tropical zone of southern Nigeria. The objective was to investigate the contribution of soil organic matter (SOM) to nutrient retention characteristics and identify those SOM pools that contribute most to the ion exchange properties of the soils. Ion exchange studies involving K-Ca and Mg-Ca systems in whole soil, organic fraction (53-250 mm) and clay fraction (<2 mm ) showed a preference for Ca relative to K in the soil and organic fraction. For the clay fraction in Alfisol, the isotherm in K-Ca system suggested a preference for K at low K saturation, but from about 50% K saturation, the isotherm inferred a preference for Ca. However, the overall selectivity at constant temperature and pressure as expressed by Gibb’s free energy change suggested a stronger binding of K than Ca by the fraction.
2 Natarajan, Rajmohan; Prathapar, Sanmugam A. 2014. Extent of arsenic contamination and its impact on the food chain and human health in the eastern Ganges Basin: a review. Colombo, Sri Lanka: International Water Management Institute (IWMI). 47p. (IWMI Working Paper 161) [doi: https://doi.org/10.5337/2014.224]
Arsenic ; Contamination ; Organic arsenic compounds ; Inorganic compounds ; Public health ; Health hazards ; Food chains ; Groundwater ; Water pollution ; Soil pollution ; Rice ; Irrigation water ; Drinking water ; Tube wells ; Ion exchange / India / Nepal / Bangladesh / Ganges Basin
(Location: IWMI HQ Call no: IWMI Record No: H046775)
(1 MB)
Exposure to arsenic and the use of arsenic-contaminated groundwater in agriculture causes serious health issues. Complete or partial contamination of groundwater is reported worldwide, especially in the Eastern Gangetic Basin (EGB). This study aims to create an overall assessment of arsenic contamination in the EGB based on existing literature, demarcate the extent of the affected area, highlight the impacts on the food chain and human health, and hopes the research will help in the better planning and management of groundwater. Although several studies have evaluated arsenic contamination of groundwater in the EGB, (a) there is no proper long-term monitoring being done in affected areas; (b) there is a debate to identify the exact source and transport processes of arsenic occurrence in this region; (c) there is no comprehensive method to estimate the level of arsenic contamination in soil, water and the food chain; and (d) Arsenic contamination in Bihar and Nepal is not evaluated systematically, especially arsenic accumulation in the food chain and human health issues. Data scarcity and accessibility are the major challenges in this region. Thus, this review recommends systematic monitoring and analysis of arsenic contamination in groundwater, soils and food across the EGB.
3 Rajmohan, N.; Patel, N.; Amarasinghe, Upali A. 2017. Hydrochemical evaluation and identification of geochemical processes in the shallow and deep wells in the Ramganga Sub-Basin, India. Environmental Science and Pollution Research, 24:21459-21475. [doi: https://doi.org/10.1007/s11356-017-9704-z]
Hydrology ; Chemical compounds ; Geochemical prospecting ; Wells ; Groundwater management ; Water quality ; River basins ; Aquifers ; Elements ; Minerals ; Ion exchange ; Contamination ; Carbonates ; Weathering / India / Ramganga Sub-Basin
(Location: IWMI HQ Call no: e-copy only Record No: H048205)
Groundwater samples were collected from 44 wells in the Ramganga Sub-Basin (RSB), India, and analysed for major ions, nutrients and trace metals. The primary goal of this study is to evaluate the hydrochemistry and to identify the geochemical processes that govern the water chemistry in the shallow and deep tube wells in the study area using geochemical methods. The knowledge of changes in hydrochemistry of the aquifers is important for both groundwater recharge and use in the region. This study found that there are substantial differences of water chemistry between shallow and deep wells. In the shallow wells, the average concentrations of total dissolved solid (TDS), Na, K, Ca, Mg, HCO3, Cl, SO4, NO3, PO4, F, Cu, Mn, Fe and Cr are twofold higher than the deep wells. The concentrations of dissolved silica in the groundwater do not vary with the depth, which implies that the variation in the water chemistry is not due to mineral dissolution alone. Major ion ratios and saturation indices suggest that the water chemistry is predominantly controlled by dissolution of carbonate minerals, silicate weathering and ion exchange reactions. Thermodynamic evaluation (ion activity ratios and stability filed diagrams) indicates that the kaolinite and gibbsite controlled the water chemistry in the both shallow and deep wells. In addition, the groundwater chemistry in the shallow wells is affected by the vertical infiltration of contaminated water from surface contamination sources and nitrification process. In the deep wells, absence of NO3 and low concentrations of Cl, SO4, PO4 and F imply the role of regional flow and denitrification in the groundwater. Results concluded that proper management plan is necessary to protect the shallow aquifer in the RSB since shallow aquifer pumping is less expensive than the deeper one.
4 Jampani, M.; Liedl, R.; Hulsmann, S.; Sonkamble, S.; Amerasinghe, Priyanie. 2020. Hydrogeochemical and mixing processes controlling groundwater chemistry in a wastewater irrigated agricultural system of India. Chemosphere, 239:124741. [doi: https://doi.org/10.1016/j.chemosphere.2019.124741]
Wastewater irrigation ; Groundwater irrigation ; Hydrology ; Geochemistry ; Aquifers ; Farming systems ; Irrigated farming ; Freshwater ; Watersheds ; Water quality ; Ion exchange ; Saturation ; Models ; Periurban areas / India / Hyderabad / Musi River Basin / Kachiwani Singaram Micro Watershed
(Location: IWMI HQ Call no: e-copy only Record No: H049333)
(2.98 MB)
In many parts of the world, wastewater irrigation has become a common practice because of freshwater scarcity and to increase resource reuse efficiency. Wastewater irrigation has positive impacts on livelihoods and at the same time, it has adverse impacts related to environmental pollution. Hydrochemical processes and groundwater behaviour need to be analyzed for a thorough understanding of the geochemical evolution in the wastewater irrigated systems. The current study focuses on a micro-watershed in the peri-urban Hyderabad of India, where farmers practice intensive wastewater irrigation. To evaluate the major factors that control groundwater geochemical processes, we analyzed the chemical composition of the wastewater used for irrigation and groundwater samples on a monthly basis for one hydrological year. The groundwater samples were collected in three settings of the watershed: wastewater irrigated area, groundwater irrigated area and upstream peri-urban area. The collected groundwater and wastewater samples were analyzed for major anions, cations and nutrients. We systematically investigated the anthropogenic influences and hydrogeochemical processes such as cation exchange, precipitation and dissolution of minerals using saturated indices, and freshwater-wastewater mixtures at the aquifer interface. Saturation indices of halite, gypsum and fluorite are exhibiting mineral dissolution and calcite and dolomite display mineral precipitation. Overall, the results suggest that the groundwater geochemistry of the watershed is largely controlled by long-term wastewater irrigation, local rainfall patterns and water-rock interactions. The study results can provide the basis for local decision-makers to develop sustainable groundwater management strategies and to control the aquifer pollution influenced by wastewater irrigation.
5 Thangarajan, M.; Singh, V. P. (Eds.) 2016. Groundwater assessment, modeling, and management. Boca Raton, FL, USA: CRC Press. 511p.
Groundwater assessment ; Groundwater management ; Models ; Water availability ; Water quality ; Water purification ; Water use ; Water resources ; Groundwater flow ; Groundwater recharge ; Alluvial aquifers ; Climate change ; Coastal area ; Water pollution ; Saline water ; Arsenic ; Contamination ; Freshwater ; Carbon dioxide ; Ion exchange ; Fluorides ; Hydraulic conductivity ; Geographical information systems ; Forecasting ; Optimization ; Food security ; Agricultural production ; Rice ; Rivers ; Hydrogeology ; Hydraulic fracturing ; Case studies / Africa South of Sahara / Southern Africa / East Africa / India / Brazil / Botswana / Okavango Delta / Cauvery River / Ganges River / Boro River Valley / Gangetic Plains / Maharashtra / Tamil Nadu
(Location: IWMI HQ Call no: e-copy SF Record No: H049342)
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