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1 Cofie, Olufunke; Pleysier, J. 2004. Ion exchange involving calcium-potasium (Ca-K) and calcium-magnesium (Ca-Mg) in soil and organic matter fractions. Communications in Soil Science and Plant Analysis, 35(17-18):2417-2431.
Ion exchange ; Soil properties ; Soil organic matter ; Clay ; Fractionation ; Calcium ; Magnesium ; Potassium / Nigeria
(Location: IWMI-HQ Call no: IWMI 631.4 G000 COF Record No: H035917)
The chemical characteristics of two soil types, an Alfisol and an Ultisol, were studied in the humid tropical zone of southern Nigeria. The objective was to investigate the contribution of soil organic matter (SOM) to nutrient retention characteristics and identify those SOM pools that contribute most to the ion exchange properties of the soils. Ion exchange studies involving K-Ca and Mg-Ca systems in whole soil, organic fraction (53-250 mm) and clay fraction (<2 mm ) showed a preference for Ca relative to K in the soil and organic fraction. For the clay fraction in Alfisol, the isotherm in K-Ca system suggested a preference for K at low K saturation, but from about 50% K saturation, the isotherm inferred a preference for Ca. However, the overall selectivity at constant temperature and pressure as expressed by Gibb’s free energy change suggested a stronger binding of K than Ca by the fraction.
2 Haroon, B.; Ping, A.; Pervez, A.; Faridullah; Irshad, M. 2019. Characterization of heavy metal in soils as affected by long-term irrigation with industrial wastewater. Journal of Water Reuse and Desalination, 9(1):47-56. [doi: https://doi.org/10.2166/wrd.2018.008]
Wastewater irrigation ; Industrial wastewater ; Irrigated soils ; Heavy metals ; Contamination ; Lead ; Nickel ; Manganese ; Copper ; Cadmium ; Iron ; Zinc ; Soil properties ; Fractionation ; Farmers / Pakistan / Hattar
(Location: IWMI HQ Call no: e-copy only Record No: H049121)
https://iwaponline.com/jwrd/article-pdf/9/1/47/522943/jwrd0090047.pdf
https://vlibrary.iwmi.org/pdf/H049121.pdf
https://vlibrary.iwmi.org/pdf/H049121.pdf
(0.21 MB) (216 KB)
Investigation of heavy metals (HM) fractions in soils irrigated with wastewater (WW) would ascertain their bioavailability and contamination level in soils. This study investigated HM fractions in soils after long-term WW irrigation. WW irrigation profoundly affected HM fractions in soil. The ranges of HM concentrations in soils irrigated with WW were apparently wide. All fractions were significantly higher in the fields irrigated with industrial WW than rain-fed fields. HM concentrations varied in the soils as Pb > Cu > Ni > Zn > Fe > Cd > Mn after WW irrigation. In rainfed fields, HM concentrations differed in soils as Fe > Zn > Mn > Pb > Cd > Cu > Ni. The HM fractions were dominant in the residual form followed by oxides bound and carbonate associated fractions in WW-irrigated soils. Lower contents of HM in the soil were obtained in the exchangeable fraction. WW irrigation resulted in the transformation of HM into different fractions as residual > oxide associated > carbonate associated > organically bound > exchangeable form. Repeated WW irrigation increased pH values of the soils. The higher EC of soil indicated an accumulation of salts in the soils due to WW irrigation. Mitigation of HM contamination in Hattar industrial effluent is required before irrigation.
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